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Butler–Volmer equation

Equation characterising electrochemical kinetics

Butler–Volmer equation

Common card · No. 358092

In electrochemistry, the Butler–Volmer equation (named after John Alfred Valentine Butler and Max Volmer), also known as Erdey-Grúz–Volmer equation (after Tibor Erdey-Grúz), is one of the most fundamental relationships in electrochemical kinetics. It describes how the electrical current through an electrode depends on the voltage difference between the electrode and the bulk electrolyte for a simple, unimolecular redox reaction, considering that both a cathodic and an anodic reaction occur on the same electrode:

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