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Scherrer equation

Formula in X-ray diffraction and crystallography

Scherrer equation

Common card · No. 479233

The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub-micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis. It is named after Paul Scherrer. It is used in the determination of size of crystals in the form of powder. The Scherrer equation can be written as: τ = K λ β cos ⁡ θ {\displaystyle \tau ={\frac {K\lambda }{\beta \cos \theta }}} where: τ {\displaystyle \tau } is the mean size of the ordered (crystalline) domains, which may be smaller or equal to the grain size; K {\displaystyle K} is a dimensionless...

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