
Tetrahedral molecular geometry
Central atom with four substituents located at the corners of a tetrahedron

Central atom with four substituents located at the corners of a tetrahedron
In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccos(−1/3) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane (CH4) as well as its heavier analogues. Methane and other perfectly symmetrical tetrahedral molecules belong to point group Td, but most tetrahedral molecules have lower symmetry. Tetrahedral molecules can be chiral.
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